Which of the following binary mixture does not show the behaviour of minimum boiling azeotropes? [JEE Main 2025, 8 Apr (…

\({\mathrm{H}}_{2}\mathrm{O}+{\mathrm{CH}}_{3}{\mathrm{COC}}_{2}{\mathrm{H}}_{5}\)

\({\mathrm{C}}_{6}{\mathrm{H}}_{5}\mathrm{OH}+{\mathrm{C}}_{6}{\mathrm{H}}_{5}{\mathrm{NH}}_{2}\)

\({\mathrm{CS}}_{2}+{\mathrm{CH}}_{3}{\mathrm{COCH}}_{3}\)

\({\mathrm{CH}}_{3}\mathrm{OH}+{\mathrm{CHCl}}_{3}\)