Consider a mixture 'X' which is made by dissolving 0.4 mol of [Co(NH 3 ) 5 SO 4 ]Br and 0.4 mol of [Co(NH 3 ) 5 Br] SO 4…
Consider a mixture 'X' which is made by dissolving 0.4 mol of [Co(NH3)5SO4]Br and 0.4 mol of [Co(NH3)5Br] SO4 in water to make 4 L of solution. When 2 L of mixture 'X' is allowed to react with excess of AgNO3, it forms precipitate 'Y'. The rest 2 L of mixture 'X' reacts with excess BaCl2 to form precipitate 'Z'. Which of the following statements is correct?
0.2 mol of 'Z' is formed.
0.4 mol [Co(NH3)5SO4]Br + 0.4 mol [Co(NH3)5 Br] SO4 are present in 4 lit. solution.
2 lit. of mixture will contain 0.2 mol of each complex.
2 lit. mixture on reaction with excess AgNO3, 0.2 mole AgBr will be formed (Y).
2 lit. mixture on reaction with excess BaCl2, 0.2 mole BaSO4 will be formed (Z).
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