Chlorine undergoes disproportionation in alkaline medium as shown below: \({\mathrm{aCl}}_{2}(\mathrm{g})+{\mathrm{bOH}}…
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Chlorine undergoes disproportionation in alkaline medium as shown below:
\({\mathrm{aCl}}_{2}(\mathrm{g})+{\mathrm{bOH}}^{−}(\mathrm{aq})\to {\mathrm{cClO}}^{−}(\mathrm{aq})+{\mathrm{dCl}}^{−}(\mathrm{aq})+{\mathrm{eH}}_{2}\mathrm{O}(\mathrm{l})\)
The values of a, b, c and d in a balanced redox reaction are respectively:
✓ Correct answer: a)
1, 2, 1 and 1
Explanation
Balanced redox equation in alkaline medium:
Cl₂ + 2OH⁻ → ClO⁻ + Cl⁻ + H₂O
To balance:
Unbalanced form given in question:
aCl₂ + bOH⁻ → cClO⁻ + dCl⁻ + eH₂O
Balanced form:
a = 1, b = 2, c = 1, d = 1, e = 1
Hence, the correct option is: A (1, 2, 1, 1).
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