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Chlorine undergoes disproportionation in alkaline medium as shown below: \({\mathrm{aCl}}_{2}(\mathrm{g})+{\mathrm{bOH}}…

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Chlorine undergoes disproportionation in alkaline medium as shown below:

\({\mathrm{aCl}}_{2}(\mathrm{g})+{\mathrm{bOH}}^{−}(\mathrm{aq})\to {\mathrm{cClO}}^{−}(\mathrm{aq})+{\mathrm{dCl}}^{−}(\mathrm{aq})+{\mathrm{eH}}_{2}\mathrm{O}(\mathrm{l})\)

The values of a, b, c and d in a balanced redox reaction are respectively:

a

1, 2, 1 and 1

b

2, 2, 1 and 3

c

3, 4, 4 and 2

d

2, 4, 1 and 3

✓ Correct answer: a)

1, 2, 1 and 1

Explanation

Balanced redox equation in alkaline medium:

Cl₂ + 2OH⁻ → ClO⁻ + Cl⁻ + H₂O

To balance:

Unbalanced form given in question:

aCl₂ + bOH⁻ → cClO⁻ + dCl⁻ + eH₂O

Balanced form:

a = 1, b = 2, c = 1, d = 1, e = 1

Hence, the correct option is: A (1, 2, 1, 1).

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