🏫 Board🧪 Chemistry

Choose the correct statement for the work done in the expansion and heat absorbed or released when 5 litres of an ideal …

Q1 FREE PREVIEW

Choose the correct statement for the work done in the expansion and heat absorbed or released when 5 litres of an ideal gas at 10 atmospheric pressure isothermally expands into vacuum until volume is 15 litres :

a

Both the heat and work done will be greater than zero.

b

Heat absorbed will be less than zero and work done will be positive.

c

Work done will be zero and heat will also be zero.

d

Work done will be greater than zero and heat will remain zero.

✓ Correct answer: c)

Work done will be zero and heat will also be zero.

Explanation

In free expansion against a vacuum, there is no external pressure resisting the expansion, so no work is done (W = 0). Since the process is isothermal for an ideal gas, there is also no net change in internal energy, so the heat exchanged (Q) is zero.

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