Thermodynamics
29 Board Chemistry previous year questions on Thermodynamics — options free on every question; 3 include the answer & explanation free, the rest unlock with PYQ Pass.
Adiabatic constant of gas is 3/2. If volume of gas initially at \({0}^{\mathrm{o}}\mathrm{C}\) is reduced to one-fourth of the original volume then new temperature is (memory based jee mains shift-1 23/01/2025)
\(546\mathrm{K}\)
In an adiabatic process, where no heat is exchanged, the relationship between temperature (T) and volume (V) for an ideal gas is given by:
T V(γ - 1) = constant, Here, γ (gamma) Adiabatic constant of gas.
T2 =546 K
Choose the correct statement for the work done in the expansion and heat absorbed or released when 5 litres of an ideal gas at 10 atmospheric pressure isothermally expands into vacuum until volume is 15 litres :
Work done will be zero and heat will also be zero.
In free expansion against a vacuum, there is no external pressure resisting the expansion, so no work is done (W = 0). Since the process is isothermal for an ideal gas, there is also no net change in internal energy, so the heat exchanged (Q) is zero.
By using relation
\(∆\mathrm{G}=∆\mathrm{H}-\mathrm{T}∆\mathrm{S}\)
Which of the following is incorrect for spontaneous reaction at a given temperature?
(Memory Based JEE Mains 23/01/2025 ,Shift -2)
\(∆\mathrm{H}>0,∆\mathrm{S}<0\)
If \(∆\mathrm{H}>0,∆\mathrm{S}>0\) then process is spontaneous at high temperature
If \(∆\mathrm{H}>0,∆\mathrm{S}<0\) process is always non spontaneous
If \(∆\mathrm{H}<0,∆\mathrm{S}>0\), then process is always spontaneous
If \(∆\mathrm{H}<0,∆\mathrm{S}<0\), then process is spontaneous at low temperature.
Adiabatic constant of gas is 3/2. If volume of gas initially at \({0}^{\mathrm{o}}\mathrm{C}\) is reduced to one-fourth of the original volume then new temperature is (memory based jee mains shift-1 23/01/2025)
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The work done during reversible isothermal expansion of one mole of hydrogen gas at \(25^\circ C\) from pressure of 20 atmosphere to 10 atmosphere is:
(Given \(\mathrm{R}=2.0\mathrm{cal}{\mathrm{K}}^{-1}{\mathrm{mol}}^{-1}\))
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In a closed insulated container, a liquid is stirred with a paddle to increase the temperature, which of the following is true?
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Identify the correct option regarding extensive and intensive property (memory based jee mains shift-2 22/01/2025)
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In which of the following processes entropy increases?
A. A liquid evaporates to vapour.
B. Temperature of a crystalline solid lowered from 130 K to 0 K.
C. \(2NaHC{O}_{3(s)}\to N{a}_{2}C{O}_{3(s)}+C{O}_{2(g)}+{H}_{2}{O}_{(g)}\)
D. \(C{l}_{2(g)}\to 2C{l}_{(g)}\)
Choose the correct answer from the options given below:
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Which of the following is not correct?
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Which of the following is not correct?
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In a closed insulated container, a liquid is stirred with a paddle to increase the temperature, which of the following is true?
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Let us consider an endothermic reaction which is non-spontaneous at the freezing point of water. However, the reaction is spontaneous at boiling point of water. Choose the correct option
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The standard Gibbs energy \(\left(∆{G}^{^\circ }\right)\) for the following reaction is \(A(s)+{B}^{+2}(aq)⇌{A}^{+2}(aq)+B(s),Kc={10}^{12}at\) (Kc = equilibrium constant)
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For an ideal monoatomic gas undergoing an isobaric process, the ratio of \(\frac{∆\mathrm{Q}}{∆\mathrm{U}}\) is (memory based jee mains shift-1 24/01/2025)
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For the following reaction at \(\mathrm{300 ~K}\)
\({A}_{2}(g)+3{B}_{2}(g)\to 2A{B}_{3}(g)\)
the enthalpy change is \(\mathrm{+15 ~kJ}\), then the internal energy change is
[Re-NEET 2024]
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The combustion of benzene (L) gives\(C{O}_{2}\) (g) and \({H}_{2}O\) (L). Given that heat of combustion of benzene at constant volume is -3263.9 kJ/mol at 25°C, heat of combustion (in kJ/mol) of benzene at constant pressure will be: (R = 8.314J\({K}^{-1}mo{l}^{-1}\))
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\(S(g)+\frac{3}{2}{O}_{2}(g)\to S{O}_{3}(g)+2xkcal\\ S{O}_{2}(g)+\frac{1}{2}{O}_{2}(g)\to S{O}_{3}(g)+ykcal\)
The heat of formation of \(S{O}_{2}(g)\) is given by
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A liquid when kept inside a thermally insulated closed vessel at 25 degree celsius was mechanically stirred from outside. What will be the correct option for the following thermodynamic parameters?
[JEE Main 2025, 22 Jan (Shift 1)]
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If \(C\) (diamond) \(\to C\) (graphite)+X \(kJmo{l}^{-1}\)
\(C(\text{ diamond })+{O}_{2}(g)\to C{O}_{2}(g)+YkJmo{l}^{-1}\)
C (graphite) \(+{O}_{2}(g)\to C{O}_{2}(g)+ZkJmo{l}^{-1}\)
at constant temperature. Then
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In the process, pressure of gas is directly proportional to temperature then choose correct option (MEMORY based jee mains shift-1 24/01/2025)
A: Process is isochoric
B: Work done in process is zero
C: Internal energy increases with increase in temperature
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Which of the following is not correct?
[JEE Main 2024, 29 Jan (Shift 1)]
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In the process, pressure of gas is directly proportional to temperature then choose correct option (MEMORY based jee mains shift-1 24/01/2025)
A: Process is isochoric
B: Work done in process is zero
C: Internal energy increases with increase in temperature
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In a closed insulated container, a liquid is stirred with a paddle to increase the temperature, which of the following is true?
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Consider the following thermochemical reaction and choose the correct option
\(\mathrm{C}(\mathrm{diamond})\to \mathrm{C}(\mathrm{graphite})+\mathrm{x}\mathrm{KJ}\\ \mathrm{C}(\mathrm{diamond})+{\mathrm{O}}_{2}\to {\mathrm{CO}}_{2}+\mathrm{y}\mathrm{KJ}\\ \mathrm{C}(\mathrm{graphite})+{\mathrm{O}}_{2}\to {\mathrm{CO}}_{2}+\mathrm{z}\mathrm{KJ}\)
29/Jan/25 Evening shift
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Identify the correct option regarding extensive and intensive property (memory based jee mains shift-2 22/01/2025)
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The correct statement amongst the following is
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For an ideal monoatomic gas undergoing an isobaric process, the ratio of \(\frac{∆\mathrm{Q}}{∆\mathrm{U}}\) is (memory based jee mains shift-1 24/01/2025)
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Given ionisation enthalpy of element \({\mathrm{E}}_{(\mathrm{g})}\) is 300 kJ / mol and electron gain enthalpy of A,B,C and D gases atoms are -320 kJ / mol,-340 kJ / mol ,-200 kJ / mol and -250 kJ / mol, then what will be the correct order of ionic nature of compounds?
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Energy supplied to 1 mole of monoatomic gas is \(48\mathrm{J}\) and changes its temperature by \(2^\circ \mathrm{C}\). Find the work done by gas.
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