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Which of the following group-15 element forms \(p\pi -p\pi\) bond and strongest basic hydride? (memory based jee mains s…

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Which of the following group-15 element forms \(p\pi -p\pi\) bond and strongest basic hydride? (memory based jee mains shift-2 28/01/2025)

a

Z=7

b

Z=15

c

Z=33

d

Z=51

✓ Correct answer: a)

Z=7

Explanation

Nitrogen (Z=7) forms strong pπ−pπ bonds (e.g., N≡N in N₂) due to its small size and effective orbital overlap. It also has the strongest basic hydride (NH₃) because of its highly available lone pair. Heavier Group-15 elements (P, As, Sb) have weaker bonding and less basic hydrides. Correct answer: (A) Z=7.

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