The complete hydrolysis of \(\mathrm{ICl},{\mathrm{ClF}}_{3}\), and \({\mathrm{BrF}}_{5}\) respectively gives [JEE Advan…
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The complete hydrolysis of \(\mathrm{ICl},{\mathrm{ClF}}_{3}\), and \({\mathrm{BrF}}_{5}\) respectively gives
[JEE Advanced 2025, Paper-2]
✓ Correct answer: a)
\(I{O}^{-},Cl{O}_{2}^{-}\text{and }Br{O}_{3}^{-}\)
Explanation
Hydrolysis of interhalogen compounds:
\(\mathrm{ICl}+{\mathrm{H}}_{2}\mathrm{O}\to \mathrm{HIO}+\mathrm{HCl}\) (produces IO–)
\({\mathrm{ClF}}_{3}+2{\mathrm{H}}_{2}\mathrm{O}\to {\mathrm{HClO}}_{2}+3\mathrm{HF}\) (produces \({\mathrm{ClO}}_{2}^{−}\))
\({\mathrm{BrF}}_{5}+3{\mathrm{H}}_{2}\mathrm{O}\to {\mathrm{HBrO}}_{3}+5\mathrm{HF}\) (produces \({\mathrm{BrO}}_{3}^{−}\))
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