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A metal complex with a formula \(\mathrm{MC}{l}_{4}\cdot 3{\mathrm{NH}}_{3}\) is involved in \({\mathrm{sp}}^{3}{\mathrm…

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A metal complex with a formula \(\mathrm{MC}{l}_{4}\cdot 3{\mathrm{NH}}_{3}\) is involved in \({\mathrm{sp}}^{3}{\mathrm{d}}^{2}\) hybridisation. It upon reaction with excess of \({\mathrm{AgNO}}_{3}\) solution gives ' x' moles of \(\mathrm{AgCl}\). Consider ' x ' is equal to the number of lone pairs of electron present in central atom of \({\mathrm{BrF}}_{5}\). Then the number of geometrical isomers exhibited by the complex is ________

[JEE Main 2025, 4 Apr (Shift 2)]

a

3

b

2

c

4

d

1

✓ Correct answer: b)

2

Explanation

One lone pair in \({\mathrm{BrF}}_{5}\)⇒ 1 mol AgCl formed.
Complex formula: \([\mathrm{M}{({\mathrm{NH}}_{3})}_{3}{\mathrm{Cl}}_{3}]\mathrm{Cl}\)
Type \({\mathrm{MA}}_{3}{\mathrm{B}}_{3}\) complex ⇒ shows 2 geometrical isomers:

  • facial (fac)

  • meridional (mer)

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