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Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two co…

Q1

Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.

[en = \({H}_{2}NC{H}_{2}C{H}_{2}N{H}_{2}\)]

[JEE Advanced 2024, Paper-1]

a

Set-I: \(\left[Ni(CO{)}_{4}\right]\) and \(\left[PdC{l}_{2}{\left(PP{h}_{3}\right)}_{2}\right]\)
Set-II: \(\left[Co{\left(N{H}_{3}\right)}_{5}Cl\right]S{O}_{4}\) and \(\left[Co{\left(N{H}_{3}\right)}_{5}\left(S{O}_{4}\right)\right]Cl\)

b

Set-I: \(\left[Co(en){\left(N{H}_{3}\right)}_{2}C{l}_{2}\right]\) and \(\left[PdC{l}_{2}{\left(PP{h}_{3}\right)}_{2}\right]\)
Set-II: \(\left[Co{\left(N{H}_{3}\right)}_{6}\right]\left[Cr(CN{)}_{6}\right]\) and \(\left[Cr{\left(N{H}_{3}\right)}_{6}\right]\left[Co(CN{)}_{6}\right]\)

c

Set-I: \(\left[Co{\left(N{H}_{3}\right)}_{3}{\left(N{O}_{2}\right)}_{3}\right]\) and \(\left[Co(\text{ en }{)}_{2}C{l}_{2}\right]\)
Set-II: \(\left[Co{\left(N{H}_{3}\right)}_{5}Cl\right]S{O}_{4}\) and \(\left[Co{\left(N{H}_{3}\right)}_{5}\left(S{O}_{4}\right)\right]Cl\)

d

Set-I: \(\left[Cr{\left(N{H}_{3}\right)}_{5}Cl\right]C{l}_{2}\) and \(\left[Co(en){\left(N{H}_{3}\right)}_{2}C{l}_{2}\right]\)
Set-II: \(\left[Cr{\left({H}_{2}O\right)}_{6}\right]C{l}_{3}\) and \(\left[Cr{\left({H}_{2}O\right)}_{5}Cl\right]C{l}_{2}.{H}_{2}O\)

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