\(\mathrm{Co}{({\mathrm{NH}}_{3})}_{\mathrm{x}}{\mathrm{Cl}}_{3}\) has 0.1 molal. 100% dissociation\(∆{\mathrm{T}}_{\mat…
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\(\mathrm{Co}{({\mathrm{NH}}_{3})}_{\mathrm{x}}{\mathrm{Cl}}_{3}\) has 0.1 molal. 100% dissociation\(∆{\mathrm{T}}_{\mathrm{f}}=0.558({\mathrm{K}}_{\mathrm{f}}=1.86)\). Then formula of the compound is
(JEE mains memory based shift-1 23/01/2025)
✓ Correct answer: c)
\(\left[\mathrm{Co}{({\mathrm{NH}}_{3})}_{5}\mathrm{Cl}\right]C{l}_{2}\)
Explanation
ΔTf = Kf ⋅ m ⋅ i and i = n ( 100% dissociation)
Where:
•ΔTf = Freezing point depression
•Kf = Freezing point depression constant
•m = Molality of the solution
•i = Van’t Hoff factor
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