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During the preparation of Mohr's salt solution (Ferrous ammonium sulphate), which of the following acid is added to prev…

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During the preparation of Mohr's salt solution (Ferrous ammonium sulphate), which of the following acid is added to prevent hydrolysis of \(F{e}^{2+}\) ion?

[NEET 2024]

a

dilute sulphuric acid

b

dilute hydrochloric acid

c

concentrated sulphuric acid

d

dilute nitric acid

✓ Correct answer: a)

dilute sulphuric acid

Explanation

Mohr’s salt (ferrous ammonium sulphate) is commonly dissolved in slightly acidic solution (using dilute H₂SO₄) to prevent oxidation and hydrolysis of Fe²⁺ ions. The acidic medium suppresses Fe²⁺→Fe³⁺ conversion and formation of insoluble iron hydroxides, ensuring the stable, clear solution of Mohr’s salt.

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