🛠️ JEE🧪 Chemistry

The correct order of basic nature on aqueous solution for the bases \({\mathrm{NH}}_{3},{\mathrm{H}}_{2}\mathrm{N}-{\mat…

Q1

The correct order of basic nature on aqueous solution for the bases \({\mathrm{NH}}_{3},{\mathrm{H}}_{2}\mathrm{N}-{\mathrm{NH}}_{2},{\mathrm{CH}}_{3}{\mathrm{CH}}_{2}{\mathrm{NH}}_{2},{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{2}\mathrm{NH}\) and \({\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{3}\mathrm{N}\) is

[JEE Main 2025, 2 Apr (Shift 1)]

a

\({\mathrm{NH}}_{3}<{\mathrm{H}}_{2}\mathrm{N}-{\mathrm{NH}}_{2}<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{3}\mathrm{N}<{\mathrm{CH}}_{3}{\mathrm{CH}}_{2}{\mathrm{NH}}_{2}\)\(<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{2}\mathrm{NH}\)

b

\({\mathrm{NH}}_{3}<{\mathrm{H}}_{2}\mathrm{N}-{\mathrm{NH}}_{2}<{\mathrm{CH}}_{3}{\mathrm{CH}}_{2}{\mathrm{NH}}_{2}<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{2}\mathrm{NH}\)\(<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{3}\mathrm{N}\)

c

\({\mathrm{H}}_{2}\mathrm{N}-{\mathrm{NH}}_{2}<{\mathrm{NH}}_{3}<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{3}\mathrm{N}<{\mathrm{CH}}_{3}{\mathrm{CH}}_{2}{\mathrm{NH}}_{2}\)\(<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{2}\mathrm{NH}\)

d

\({\mathrm{NH}}_{2}-{\mathrm{NH}}_{2}<{\mathrm{NH}}_{3}<{\mathrm{CH}}_{3}{\mathrm{CH}}_{2}{\mathrm{NH}}_{2}<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{3}\mathrm{N}\)\(<{\left({\mathrm{CH}}_{3}{\mathrm{CH}}_{2}\right)}_{2}\mathrm{NH}\)

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