🛠️ JEE🧪 Chemistry

At the sea level, the dry air mass percentage composition is given as nitrogen gas : \(70.0\), oxygen gas : \(27.0\) and…

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At the sea level, the dry air mass percentage composition is given as nitrogen gas : \(70.0\), oxygen gas : \(27.0\) and argon gas : \(3.0\). If total pressure is \(1.15\) atm, then calculate the ratio of followings respectively :
(i) partial pressure of nitrogen gas to partial pressure of oxygen gas
(ii) partial pressure of oxygen gas to partial pressure of argon gas
(Given : Molar mass of N, O and Ar are \(14,16,\) and \(40\mathrm{g}{\mathrm{mol}}^{-1}\) respectively)

[JEE Main 2025, 7 Apr (Shift 1)]

a

4.26, 19.3

b

2.59, 11.85

c

5.46, 17.8

d

2.96, 11.2

✓ Correct answer: d)

2.96, 11.2

Explanation

\(\frac{{P}_{{N}_{2}}}{{P}_{{O}_{2}}}=\frac{{X}_{{N}_{2}}.{P}_{T}}{{X}_{{O}_{2}}.{P}_{T}}=\frac{n{N}_{2}}{{n}_{{O}_{2}}}\)\(=\frac{70/28}{27/32}=2.96\)\(\frac{{P}_{{O}_{2}}}{{P}_{Ar}}=\frac{{n}_{{O}_{2}}}{{n}_{Ar}}=\frac{27/32}{3/40}=11.25\)

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