JEEChemistry

Some Basic Concepts of Chemistry

94 JEE Chemistry previous year questions on Some Basic Concepts of Chemistry — options free on every question; 9 include the answer & explanation free, the rest unlock with PYQ Pass.

Q1 FREE PREVIEW
PYQ
A metal chloride contains 55.0% of chlorine by weight. 100 mL vapours of the metal chloride at STP weigh 0.57 g. The molecular formula of the metal chloride is (Given: Atomic mass of chlorine is 35.5 u)
aMCl2
bMCl4
cMCl3
dMCl
✓ Correct answer: a) MCl2
ExplanationGiven: Mass = 0.57 g, Volume = 100 mL = 0.1 L At STP, molar volume = 22.4 L Moles = 0.1 / 22.4 = 0.004464 mol Molar mass = 0.57 / 0.004464 ≈ 127.7 g/mol Let metal chloride be MClₓ %Cl = (35.5x / (M + 35.5x)) × 100 = 55 Putting M + 35.5x = 127.7, solve: 35.5x = 70.24 ⇒ x = 2 So formula = MCl₂ Answer: Option A
Q2 FREE PREVIEW
PYQ

Choose the correct statements.
(A) Weight of a substance is the amount of matter present in it.
(B) Mass is the force exerted by gravity on an object.
(C) Volume is the amount of space occupied by a substance.
(D) Temperatures below \(0^\circ C\) are possible in Celsius scale, but in Kelvin scale negative temperature is not possible.
(E) Precision refers to the closeness of various measurements for the same quantity.

Choose the correct answer from the options given below

a

(B), (C) and (D) Only

b

(C), (D) and (E) Only

c

(A), (B) and (C) Only

d

(A), (D) and (E) Only

✓ Correct answer: b)

(C), (D) and (E) Only

Explanation

Weight is the force of gravity on an object, while mass is the amount of matter.

Q3 FREE PREVIEW
PYQ

Among \({10}^{-9}\mathrm{g}\) (each) of the following elements, which one will have the highest number of atoms?

Element : \(\mathrm{Pb},\mathrm{Po},\mathrm{Pr}\) and \(\mathrm{Pt}\)

[JEE Main 2025, 3 Apr (Shift 1)]

a

Po

b

Pr

c

Pb

d

Pt

✓ Correct answer: b)

Pr

Explanation

For the same mass, element having the least Molar mass will have the higher no. of atoms.

M.MPo = 209 g mol-1

M.MPr = 141 g mol-1

M.MPb = 207 g mol-1

M.MPt = 195 g mol-1

Q4 FREE PREVIEW
PYQ

0.1 M solution of KI reacts with excess of \({H}_{2}S{O}_{4}\) and \(KI{O}_{3}\) solutions. According to equation

\(5{I}^{-}+I{O}_{3}^{-}+6{H}^{+}\to 3{I}_{2}+3{H}_{2}O\)

Identify the correct statements :
(A) 200 mL of KI solution reacts with 0.004 mol of \(KI{O}_{3}\)
(B) 200 mL of KI solution reacts with 0.006 mol of \({H}_{2}S{O}_{4}\)
(C) 0.5 L of KI solution produced 0.005 mol of \({I}_{2}\)
(D) Equivalent weight of \(KI{O}_{3}\) is equal to (\(\frac{\text{ Molecular weight }}{5}\))

Choose the correct answer from the options given below

a

(A) and (B) only

b

(A) and (D) only

c

(B) and (C) only

d

(C) and (D) only

✓ Correct answer: b)

(A) and (D) only

Explanation

\(200mL(0.2L)\) of KI solution \((0.1M)\)
\(\to\) Moles of Kl (I)

\(=0.1\times 0.2=0.02\text{ moles }.\)

From reaction: 5 moles of \({I}^{-}\)react with 1 mole of \(I{O}_{3}^{-}\).
Required \(I{O}_{3}^{-}:0.02\times 1/5=0.004\) moles.

Equivalent weight formula:

\(\text{ Equivalent weight }=\frac{\text{ Molecular weight }}{n-\text{ factor }}\)

For \(I{O}_{3}^{-}\)in this reaction, the change in oxidation state ( n -factor) is 5 .
Hence, Equivalent weight =( Molecular weight)/5.

Q5 FREE PREVIEW
PYQ

0.1 M solution of KI reacts with excess of \({H}_{2}S{O}_{4}\) and \(KI{O}_{3}\) solutions. According to equation

\(5{I}^{-}+I{O}_{3}^{-}+6{H}^{+}\to 3{I}_{2}+3{H}_{2}O\)

Identify the correct statements :
(A) 200 mL of KI solution reacts with 0.004 mol of \(KI{O}_{3}\)
(B) 200 mL of KI solution reacts with 0.006 mol of \({H}_{2}S{O}_{4}\)
(C) 0.5 L of KI solution produced 0.005 mol of \({I}_{2}\)
(D) Equivalent weight of \(KI{O}_{3}\) is equal to (\(\frac{\text{ Molecular weight }}{5}\))

Choose the correct answer from the options given below.

[JEE Main 2025, 29 Jan (Shift 2)]

a

(A) and (B) only

b

(A) and (D) only

c

(B) and (C) only

d

(C) and (D) only

✓ Correct answer: b)

(A) and (D) only

Explanation

\(200mL(0.2L)\) of KI solution \((0.1M)\)
\(\to\) Moles of KI (I)

\(=0.1\times 0.2=0.02\text{ moles }.\)

From reaction: 5 moles of \({I}^{-}\)react with 1 mole of \(I{O}_{3}^{-}\).
Required \(I{O}_{3}^{-}:0.02\times 1/5=0.004\) moles.

Equivalent weight formula:

\(\text{ Equivalent weight }=\frac{\text{ Molecular weight }}{n-\text{ factor }}\)

For \(I{O}_{3}^{-}\)in this reaction, the change in oxidation state ( n -factor) is 5 .
Hence, Equivalent weight =( Molecular weight)/5.

Q6 FREE PREVIEW
PYQ

Given below are two statements.

Statement-I: One mole of propyne reacts with excess of sodium to liberate half a mole of hydrogen gas.

Statement-II: Four grams of propyne reacts with sodium amide to liberate ammonia gas which occupies 224 mL at STP.

In the light of above statements, choose most appropriate answer from options given below

[JEE Main 2025, 22 Jan (Shift 1)]

a

Statement-I is correct but statement-II is incorrect

b

Both statement-I and statement-II are incorrect

c

Statement-I is incorrect but statement-II is correct

d

Both statement-I and statement-II are correct

✓ Correct answer: a)

Statement-I is correct but statement-II is incorrect

Explanation

\({\mathrm{CH}}_{3}-\mathrm{C}\equiv \mathrm{CH}+\mathrm{Na}\to {\mathrm{CH}}_{3}-\mathrm{C}\equiv \overset{-}{\mathrm{C}}\overset{+}{\mathrm{Na}}+\frac{1}{2}{\mathrm{H}}_{2}\\ 1\mathrm{mole}\mathrm{of}\mathrm{propyne}\mathrm{gives}0.5\mathrm{mole}\mathrm{of}\mathrm{hydrogen}\mathrm{gas}\\ {\mathrm{CH}}_{3}-\mathrm{C}\equiv \mathrm{CH}+{\mathrm{NaNH}}_{2}\to {\mathrm{CH}}_{3}-\mathrm{C}\equiv \overset{-}{\mathrm{C}}\overset{+}{\mathrm{Na}}+{\mathrm{NH}}_{3}\\ \mathrm{n}=\frac{4\mathrm{g}}{40\mathrm{g}}=0.1\mathrm{mole}\\ 1\mathrm{mole}\mathrm{occupies}22400\mathrm{ml}\\ \mathrm{So},0.1\mathrm{mole}\mathrm{occupies}2240\mathrm{ml}\)

Q7 FREE PREVIEW
PYQ

An organic compound weighing 500 mg produced 220 mg of \({\mathrm{CO}}_{2}\) on complete combustion. The percentage composition of carbon in the compound is _____%. (nearest integer)
(Given molar mass in g mol–1 of C : 12, O : 16)

[JEE Main 2025, 7 Apr (Shift 1)]

a

10

b

12

c

14

d

16

✓ Correct answer: b)

12

Explanation

\(\text{Organic compound }\overset{\mathrm{C}\mathrm{u}\mathrm{O}}{\underset{\Delta }{\to }}{\mathrm{C}\mathrm{O}}_{2}+{\mathrm{H}}_{2}\mathrm{O}\)

\({\mathrm{n}}_{{\mathrm{CO}}_{2}}=\frac{220\times {10}^{−3}}{44}=5\times {10}^{−3}\text{ }moles\)

\({\mathrm{m}}_{\mathrm{C}}=5\times {10}^{−3}\times 12\)

\(\mathrm{\%}\text{ }carbon=\frac{5\times {10}^{−3}\times 12}{500\times {10}^{−3}}\times 100=12\mathrm{\%}\)

Q8 FREE PREVIEW
PYQ

The hydrocarbon (𝑋) with molar mass 80 g \(mol{}^{-1}\) and 90% carbon has ______ degree of unsaturation.

[JEE Main 2025, 24 Jan (Shift 2)]

a

1

b

2

c

3

d

4

✓ Correct answer: c)

3

Explanation

First calculate no. of Carbon and H atoms as:
Mass of carbon \(=\frac{80\times 90}{100}=72g\)
Number of C-atoms \(=\frac{72}{12}=6\)
Mass of hydrogen =80-72=8 g
Number of H -atoms \(=\frac{8}{1}=8\)
Molecular formula of hydrocarbon

\(={C}_{6}{H}_{8}\)

Degree of unsaturation =12+2-8 / 2=3

Q9 FREE PREVIEW
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

[JEE Main 2024, 4 Apr (Shift 2)]

a

All the atoms of a given element have identical properties including identical mass.

b

Chemical reactions involve reorganization of atoms

c

Compounds are formed when atoms of different elements combine in any ratio.

d

Matter consists of indivisible atoms.

✓ Correct answer: c)

Compounds are formed when atoms of different elements combine in any ratio.

Explanation

According to Dalton's Atomic Theory,
compounds are formed when atoms of different elements combine in a fixed (definite) ratio by mass and number.
So, saying they combine in "any" ratio is incorrect.

Q10
PYQ

\({\mathrm{CaCO}}_{3}(\mathrm{s})+2\mathrm{HCl}(\mathrm{aq})\to\)\({\mathrm{CaCl}}_{2}(\mathrm{aq})+{\mathrm{CO}}_{2}(\mathrm{g}){\mathrm{H}}_{2}\mathrm{O}(\mathrm{l})\)
Consider the above reaction, what mass of \({\mathrm{CaCl}}_{2}\) will be formed if \(250\) mL of \(0.76\mathrm{M}\) reacts with \(1000\) g of \({\mathrm{CaCO}}_{3}\) ?
(Given : Molar mass of \(\mathrm{Ca},\mathrm{C},\mathrm{O},\mathrm{H}\) and \(\mathrm{Cl}\) are \(40,12,16,1\) and \(35.5\mathrm{g}{\mathrm{mol}}^{-1}\), respectively)

[JEE Main 2025, 2 Apr (Shift 1)]

a

\(3.908g\)

b

\(2.636g\)

c

\(10.545g\)

d

\(5.272g\)

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Q11
PYQ

Choose the correct statements.
(A) Weight of a substance is the amount of matter present in it.
(B) Mass is the force exerted by gravity on an object.
(C) Volume is the amount of space occupied by a substance.
(D) Temperatures below \(0^\circ C\) are possible in Celsius scale, but in Kelvin scale negative temperature is not possible.
(E) Precision refers to the closeness of various measurements for the same quantity.

Choose the correct answer from the options given below.

a

(B), (C) and (D) Only

b

(C), (D) and (E) Only

c

(A), (B) and (C) Only

d

(A), (D) and (E) Only

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Q12
PYQ

An organic compound has 42.1% carbon, 6.4% hydrogen and remainder is oxygen. If its molecular weight is 342, then its molecular formula is:

a

C11H18O12

b

C12H20O12

c

C14H20O10

d

C11H22O11

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Q13
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Mass of magnesium required to produce \(220\mathrm{mL}\) of hydrogen gas at STP on reaction with excess of dil. HCl is
Given : Molar mass of Mg is \(24\mathrm{g}{\mathrm{mol}}^{-1}\).

a

\(235.7\mathrm{g}\)

b

\(0.24\mathrm{mg}\)

c

\(235.7\mathrm{mg}\)

d

\(2.444\mathrm{g}\)

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Q14
PYQ

The incorrect postulates of the Dalton's atomic theory are:

(A) Atoms of different elements differ in mass.

(B) Matter consists of divisible atoms.

(C) Compounds are formed when atoms of different element combine in a fixed ratio.

(D) All the atoms of given element have different properties including mass.

(E) Chemical reactions involve reorganisation of atoms.

Choose the correct answer from the options given below:

a

(B), (D), (E) only

b

(A), (B), (D) only

c

(C), (D), (E) only

d

(B), (D) only

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Q15
PYQ

Choose the correct statements.
(A) Weight of a substance is the amount of matter present in it.
(B) Mass is the force exerted by gravity on an object.
(C) Volume is the amount of space occupied by a substance.
(D) Temperatures below \(0^\circ C\) are possible in Celsius scale, but in Kelvin scale negative temperature is not possible.
(E) Precision refers to the closeness of various measurements for the same quantity.

Choose the correct answer from the options given below

a

(B), (C) and (D) Only

b

(C), (D) and (E) Only

c

(A), (B) and (C) Only

d

(A), (D) and (E) Only

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Q16
PYQ

The quantity which changes with temperature is:

a

Mole fraction

b

Molality

c

Molarity

d

Mass percentage

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Q17
PYQ

Concentrated nitric acid is labelled as 75 % by mass. The volume in mL of the solution which contains 30 g of nitric acid is_____
Given : Density of nitric acid solution is 1.25 g/mL.

[JEE Main 2025, 28 Jan (Shift 1)]

a

45

b

55

c

32

d

40

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Q18
PYQ

\(2.8\times {10}^{-3}\mathrm{mol}\mathrm{of}{\mathrm{CO}}_{2}\)is left after removing \({10}^{21}\)molecules from its ' x ' mg sample. The mass of \({\mathrm{CO}}_{2}\) taken initially is

(Given : \({\mathrm{N}}_{\mathrm{A}}=6.02\times {10}^{23}{\mathrm{mol}}^{-1}\))

[JEE Main 2025, 23 Jan (Shift 1)]

a

48.2 mg

b

98.3 mg

c

150.4 mg

d

196.2 mg

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Q19
PYQ

10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume upto the mark with distilled water. The solution in this flask is

[JEE Main 2025, 3 Apr (Shift 2)]

a

0.2 M NaCl solution

b

20 M HCl solution

c

10 M HCl solution

d

Neutral solution

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Q20
PYQ

7.3 g of benzalacetone is synthesized from 10.6 g of benzaldehyde using acetone as another reactant. Percentage yield of benzalacetone is (memory based jee mains shift-2 29/01/2025)

a

50%

b

27%

c

90%

d

40%

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Q21
PYQ

On combustion \(0.210\)g of an orgainc compound containing \(\mathrm{C},\mathrm{H}\) and \(O\) gave \(0.127\mathrm{g}{\mathrm{H}}_{2}\mathrm{O}\) and \(0.307\mathrm{g}{\mathrm{CO}}_{2}\). The percentages of hydrogen and oxygen in the given organic compound respectively are

[JEE Main 2025, 8 Apr (Shift 1)]

a

\(53.41,39.6\)

b

\(6.72,53.41\)

c

\(7.55,43.85\)

d

\(6.72,39.87\)

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Q22
PYQ

Density of 3 M NaCl solution is 1.25 g/mL. The molality of the solution is

a

1.79 m

b

2.79 m

c

3.2 m

d

4.3 m

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Q23
PYQ

\(10 mL\) of gaseous hydrocarbon on combustion gives \(40 mL\) of \(CO _2( g )\) and \(50 mL\) of water vapour. The sum of number of carbon and hydrogen atoms in the hydrocarbon is___________

a

11

b

12

c

13

d

14

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Q24
PYQ

On complete combustion \(1.0\) g of an organic compound (X) gave \(1.46g\) of \({\mathrm{CO}}_{2}\) and \(0.567\) g of \({\mathrm{H}}_{2}\mathrm{O}\). The empirical formula mass of compound (X) is _______ g .
(Given molar mass in \({\mathrm{gmol}}^{-1}\mathrm{C}:12,\mathrm{H}:1,\mathrm{O}:16\) )

[JEE Main 2025, 2 Apr (Shift 1)]

a

\(30\)

b

\(45\)

c

\(60\)

d

\(15\)

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Q25
PYQ

Number of moles of methane required to produce 22 g \(CO _{2( g )}\) after combustion is \(x \times 10^{-2}\) moles. The value of \(x\) is ......... .

a

50

b

60

c

70

d

80

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Q26
PYQ

\(0.5\)g of an organic compound on combustion gave \(1.46g\) of \({\mathrm{CO}}_{2}\) and \(0.9g\) of \({\mathrm{H}}_{2}\mathrm{O}\). The percentage of carbon in the compound is ______%. (Nearest integer)
[Given : Molar mass (in \({\mathrm{gmol}}^{-1}\)) \(\mathrm{C}:12,\mathrm{H}:1,\mathrm{O}:16\)]

[JEE Main 2025, 3 Apr (Shift 1)]

a

70

b

75

c

80

d

85

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Q27
PYQ

Density of 3 M NaCl solution is 1.25 g/mL. The molality of the solution is

a

1.79 m

b

2.79 m

c

3.2 m

d

4.3 m

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Q28
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

[JEE Main 2024, 4 Apr (Shift 2)]

a

All the atoms of a given element have identical properties including identical mass.

b

Chemical reactions involve reorganization of atoms

c

Compounds are formed when atoms of different elements combine in any ratio.

d

Matter consists of indivisible atoms.

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Q29
PYQ

The incorrect postulates of the Dalton's atomic theory are

(a) Atoms of different elements differ in mass.
(b) Matter consists of divisible atoms.
(c) Compounds are formed when atoms of different element combine in a fixed ratio.
(d) All the atoms of a given element have different properties including mass.
(e) Chemical reactions involve reorganisation of atoms.

Choose the correct answer from the options given below

a

(b), (d), (e) only

b

(b), (d) only

c

(a), (b), (d) only

d

(c), (d), (e) only

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Q30
PYQ

The incorrect postulates of the Dalton's atomic theory are

(a) Atoms of different elements differ in mass.
(b) Matter consists of divisible atoms.
(c) Compounds are formed when atoms of different element combine in a fixed ratio.
(d) All the atoms of a given element have different properties including mass.
(e) Chemical reactions involve reorganisation of atoms.

Choose the correct answer from the options given below

a

(b), (d), (e) only

b

(b), (d) only

c

(a), (b), (d) only

d

(c), (d), (e) only

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Q31
PYQ

Mass of magnesium required to produce \(220\mathrm{mL}\) of hydrogen gas at STP on reaction with excess of dil. HCl is
Given : Molar mass of Mg is \(24\mathrm{g}{\mathrm{mol}}^{-1}\).

[JEE Main 2025, 3 Apr (Shift 2)]

a

\(235.7\mathrm{g}\)

b

\(0.24\mathrm{mg}\)

c

\(236\mathrm{mg}\)

d

\(2.444\mathrm{g}\)

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Q32
PYQ

The number of moles of methane required to produce 11g CO2(g) after complete combustion is: (Given molar mass of methane in \(\mathrm{g}{\mathrm{mol}}^{-1}:16\))

a

0.75

b

0.5

c

0.35

d

0.25

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Q33
PYQ

In a compound contains 54.2 % carbon, 9.2 % of hydrogen and rest are oxygen. What is molecular formula of compound, if molecular mass is 132 g/mol ?
(Memory Based JEE Mains 24/01/2025 ,Shift -2)

a

\({\mathrm{C}}_{6}{\mathrm{H}}_{12}{\mathrm{O}}_{3}\)

b

\({\mathrm{C}}_{4}{\mathrm{H}}_{12}{\mathrm{O}}_{3}\)

c

\({\mathrm{C}}_{4}{\mathrm{H}}_{12}{\mathrm{O}}_{6}\)

d

\({\mathrm{C}}_{6}{\mathrm{H}}_{13}{\mathrm{O}}_{3}\)

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Q34
PYQ

The incorrect postulates of the Dalton's atomic theory are:

(A) Atoms of different elements differ in mass.

(B) Matter consists of divisible atoms.

(C) Compounds are formed when atoms of different element combine in a fixed ratio.

(D) All the atoms of given element have different properties including mass.

(E) Chemical reactions involve reorganisation of atoms.

Choose the correct answer from the options given below:

a

(B), (D), (E) only

b

(A), (B), (D) only

c

(C), (D), (E) only

d

(B), (D) only

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Q35
PYQ

A sample of \(\mathrm{CaCO}_3\) and \(\mathrm{MgCO}_3\) weighed \(2.21 \mathrm{~g}\) is ignited to constant weight of \(1.152 \mathrm{~g}\). The composition of mixture is : (Given molar mass in \(\mathrm{g} \mathrm{mol}^{-1} \mathrm{CaCO}_3: 100, \mathrm{MgCO}_3: 84\) )

a

\(1.187 \mathrm{~g} \mathrm{~CaCO}_3+1.023 \mathrm{~g} \mathrm{~MgCO}_3\)

b

\(1.023 \mathrm{~g} \mathrm{~CaCO}_3+1.187 \mathrm{~g} \mathrm{~MgCO}_3\)

c

\(1.023 \mathrm{~g} \mathrm{~CaCO}_3+1.023 \mathrm{~g} \mathrm{~MgCO}_3\)

d

\(1.187 \mathrm{~g} \mathrm{~CaCO}_3+1.187 \mathrm{~g} \mathrm{~MgCO}_3\)

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Q36
PYQ

A sample of \(\mathrm{CaCO}_3\) and \(\mathrm{MgCO}_3\) weighed \(2.21 \mathrm{~g}\) is ignited to constant weight of \(1.152 \mathrm{~g}\). The composition of mixture is : (Given molar mass in \(\mathrm{g} \mathrm{mol}^{-1} \mathrm{CaCO}_3: 100, \mathrm{MgCO}_3: 84\) )

a

\(1.187 \mathrm{~g} \mathrm{~CaCO}_3+1.023 \mathrm{~g} \mathrm{~MgCO}_3\)

b

\(1.023 \mathrm{~g} \mathrm{~CaCO}_3+1.187 \mathrm{~g} \mathrm{~MgCO}_3\)

c

\(1.023 \mathrm{~g} \mathrm{~CaCO}_3+1.023 \mathrm{~g} \mathrm{~MgCO}_3\)

d

\(1.187 \mathrm{~g} \mathrm{~CaCO}_3+1.187 \mathrm{~g} \mathrm{~MgCO}_3\)

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Q37
PYQ

On complete combustion \(1.0\) g of an organic compound (X) gave \(1.46g\) of \({\mathrm{CO}}_{2}\) and \(0.567\) g of \({\mathrm{H}}_{2}\mathrm{O}\). The empirical formula mass of compound (X) is _______ g .
(Given molar mass in \({\mathrm{gmol}}^{-1}\mathrm{C}:12,\mathrm{H}:1,\mathrm{O}:16\) )

[JEE Main 2025, 2 Apr (Shift 1)]

a

\(30\)

b

\(45\)

c

\(60\)

d

\(15\)

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Q38
PYQ

The mass of iron converted into \(F{e}_{3}{O}_{4}\) by the action of 18 g of steam is:
(Given: Molar mass of H , O and Fe are 1,16 and \(56gmo{l}^{-1}\) respectively)
Assume iron is present in excess:
[JEE Main 2026, 2 April, shift-1]

a

2.1g

b

4.2g

c

21g

d

42g

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Q39
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

a

Compounds are formed when atoms of different elements combine in any ratio

b

All the atoms of a given element have identical properties including identical mass

c

Matter consists of indivisible atoms

d

Chemical reactions involve reorganization of atoms

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Q40
PYQ

The correct name of I & II in the following process is :

Solid \(\overset{\mathrm{I}}{\to }\)Vapours\(\overset{\mathrm{II}}{\to }\)Solid
Memory Based Question 28/Jan/25 Evening shift

a

I \(\to\)Sublimation

II \(\to\)Vaporisation

b

I Sublimation

II Decomposition

c

I Sublimation

II Deposition

d

I Deposition

II Sublimation

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Q41
PYQ

If a substance ' \(A\) ' dissolves in solution of a mixture of ' \(B\) ' and ' \(C\) ' with their respective number of moles as \(n _{ A }, n _{ B }\) and \(n _{ C }\). Mole fraction of \(C\) in the solution is

[JEE Main 2024, 30 Jan (Shift 2)]

a

\(\frac{n_C}{n_A-n_B-n_C}\)

b

\(\frac{n_C}{n_A \times n_B \times n_C}\)

c

\(\frac{ n _{ B }}{ n _{ A }+ n _{ B }}\)

d

\(\frac{n_C}{n_A+n_B+n_C}\)

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Q42
PYQ

Concentrated nitric acid is labelled as 75 % by mass. The volume in mL of the solution which contains 30 g of nitric acid is_____
Given : Density of nitric acid solution is 1.25 g/mL.

a

45

b

55

c

32

d

40

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Q43
PYQ

Butane reacts with oxygen to produce carbon dioxide and water following the equation given below
\({\mathrm{C}}_{4}{\mathrm{H}}_{10}(\mathrm{g})+\frac{13}{2}{\mathrm{O}}_{2}(\mathrm{g})\to 4{\mathrm{CO}}_{2}(\mathrm{g})+5{\mathrm{H}}_{2}\mathrm{O}(\mathrm{l})\)
If \(174.0\)kg of butane is mixed with \(320.0\) kg of \({\mathrm{O}}_{2}\), the volume of water formed in litres is ________ .(Nearest integer)
[Given : (a) Molar mass of \(\mathrm{C},\mathrm{H},\mathrm{O}\)are 12, 1, \(16\mathrm{g}{\mathrm{mol}}^{-1}\) respectively, (b) Density of water \(\left.=1\mathrm{g}{\mathrm{mL}}^{-1}\right]\)

[JEE Main 2025, 7 Apr (Shift 2)]

a

138

b

140

c

142

d

144

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Q44
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

[JEE Main 2024, 4 Apr (Shift 2)]

a

All the atoms of a given element have identical properties including identical mass.

b

Chemical reactions involve reorganization of atoms

c

Compounds are formed when atoms of different elements combine in any ratio.

d

Matter consists of indivisible atoms.

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Q45
PYQ

\({\mathrm{CaCO}}_{3}(\mathrm{s})+2\mathrm{HCl}(\mathrm{aq})\to\)\({\mathrm{CaCl}}_{2}(\mathrm{aq})+{\mathrm{CO}}_{2}(\mathrm{g})+{\mathrm{H}}_{2}\mathrm{O}(\mathrm{l})\)

Consider the above reaction, what mass of \({\mathrm{CaCl}}_{2}\) will be formed if \(250\) mL of \(0.76\mathrm{M}\) reacts with \(1000\) g of \({\mathrm{CaCO}}_{3}\) ?
(Given : Molar mass of \(\mathrm{Ca},\mathrm{C},\mathrm{O},\mathrm{H}\) and \(\mathrm{Cl}\) are \(40,12,16,1\) and \(35.5\mathrm{g}{\mathrm{mol}}^{-1}\), respectively)

[JEE Main 2025, 2 Apr (Shift 1)]

a

\(3.908g\)

b

\(2.636g\)

c

\(10.545g\)

d

\(5.272g\)

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Q46
PYQ

Among \({10}^{-9}\mathrm{g}\) (each) of the following elements, which one will have the highest number of atoms?

Element : \(\mathrm{Pb},\mathrm{Po},\mathrm{Pr}\) and \(\mathrm{Pt}\)

[JEE Main 2025, 3 Apr (Shift 1)]

a

Po

b

Pr

c

Pb

d

Pt

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Q47
PYQ

An organic compound has 42.1% carbon, 6.4% hydrogen and remainder is oxygen. If its molecular weight is 342, then its molecular formula is:

a

C11H18O12

b

C12H20O12

c

C14H20O10

d

C12H22O11

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Q48
PYQ

10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume upto the mark with distilled water. The solution in this flask is

[JEE Main 2025, 3 Apr (Shift 2)]

a

0.2 M NaCl solution

b

20 M HCl solution

c

10 M HCl solution

d

Neutral solution

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Q49
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

a

All the atoms of a given element have identical properties including identical mass.

b

Chemical reactions involve reorganization of atoms

c

Compounds are formed when atoms of different elements combine in any ratio.

d

Matter consists of indivisible atoms.

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Q50
PYQ

The quantity which changes with temperature is:

a

Mole fraction

b

Molality

c

Molarity

d

Mass percentage

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Q51
PYQ

Concentrated nitric acid is labelled as 75 % by mass. The volume in mL of the solution which contains 30 g of nitric acid is_____
Given : Density of nitric acid solution is 1.25 g/mL.

[JEE Main 2025, 28 Jan (Shift 1)]

a

45

b

55

c

32

d

40

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Q52
PYQ

\(2.8\times {10}^{-3}\mathrm{mol}\mathrm{of}{\mathrm{CO}}_{2}\)is left after removing \({10}^{21}\)molecules from its ' x ' mg sample. The mass of \({\mathrm{CO}}_{2}\) taken initially is

(Given : \({\mathrm{N}}_{\mathrm{A}}=6.02\times {10}^{23}{\mathrm{mol}}^{-1}\))

a

48.2 mg

b

98.3 mg

c

150.4 mg

d

196.2 mg

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Q53
PYQ

The amount of calcium oxide produced on heating \(150\) kg limestone (\(75\%\) pure) is ______ kg. (Nearest integer)
Given : Molar mass (in \({\mathrm{gmol}}^{-1}\) ) of \(\mathrm{Ca}-40,\mathrm{O}-16,\mathrm{C}-12\)

[JEE Main 2025, 4 Apr (Shift 2)]

a

61

b

63

c

65

d

67

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Q54
PYQ

Choose the correct statements.
(A) Weight of a substance is the amount of matter present in it.
(B) Mass is the force exerted by gravity on an object.
(C) Volume is the amount of space occupied by a substance.
(D) Temperatures below \(0^\circ C\) are possible in Celsius scale, but in Kelvin scale negative temperature is not possible.
(E) Precision refers to the closeness of various measurements for the same quantity.

Choose the correct answer from the options given below

[JEE Main 2025, 29 Jan (Shift 1)]

a

(B), (C) and (D) Only

b

(C), (D) and (E) Only

c

(A), (B) and (C) Only

d

(A), (D) and (E) Only

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Q55
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

a

Compounds are formed when atoms of different elements combine in any ratio

b

All the atoms of a given element have identical properties including identical mass

c

Matter consists of indivisible atoms

d

Chemical reactions involve reorganization of atoms

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Q56
PYQ

Concentrated nitric acid is labelled as 75 % by mass. The volume in mL of the solution which contains 30 g of nitric acid is_____
Given : Density of nitric acid solution is 1.25 g/mL

a

45

b

55

c

32

d

40

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Q57
PYQ

Which of the following mixing of 1 M base and 1 M acid leads to the largest increase in temperature?

[JEE Main 2025, 24 Jan (Shift 2)]

a

\(45\mathrm{mL}{\mathrm{CH}}_{3}\mathrm{COOH}\) and 25 mL NaOH

b

\(30\mathrm{mL}{\mathrm{CH}}_{3}\mathrm{CHCOOH}\) and 30 mL NaOH

c

50 mL HCl and 20 mL NaOH

d

30 mL HCl and 30 mL NaOH

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Q58
PYQ

The mass of sodium acetate (CH3COONa) required to prepare 250 mL of 0.35 M aqueous solution is_____ g. (Molar mass of CH3COONa is 82.02 g mol–1) (Nearest integer)

a

5

b

7

c

9

d

11

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Q59
PYQ

Choose the correct statements.
(A) Weight of a substance is the amount of matter present in it.
(B) Mass is the force exerted by gravity on an object.
(C) Volume is the amount of space occupied by a substance.
(D) Temperatures below \(0^\circ C\) are possible in Celsius scale, but in Kelvin scale negative temperature is not possible.
(E) Precision refers to the closeness of various measurements for the same quantity.

Choose the correct answer from the options given below

a

(B), (C) and (D) Only

b

(C), (D) and (E) Only

c

(A), (B) and (C) Only

d

(A), (D) and (E) Only

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Q60
PYQ

Given below are two statements.

Statement-I: One mole of propyne reacts with excess of sodium to liberate half a mole of hydrogen gas.

Statement-II: Four grams of propyne reacts with sodium amide to liberate ammonia gas which occupies 224 mL at STP.

In the light of above statements, choose most appropriate answer from options given below

[JEE Main 2025, 22 Jan (Shift 1)]

a

Statement-I is correct but statement-II is incorrect

b

Both statement-I and statement-II are incorrect

c

Statement-I is incorrect but statement-II is correct

d

Both statement-I and statement-II are correct

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Q61
PYQ

On combustion \(0.210\)g of an orgainc compound containing \(\mathrm{C},\mathrm{H}\) and \(O\) gave \(0.127\mathrm{g}{\mathrm{H}}_{2}\mathrm{O}\) and \(0.307\mathrm{g}{\mathrm{CO}}_{2}\). The percentages of hydrogen and oxygen in the given organic compound respectively are

[JEE Main 2025, 8 Apr (Shift 1)]

a

\(53.41,39.6\)

b

\(6.72,53.41\)

c

\(7.55,43.85\)

d

\(6.72,39.87\)

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Q62
PYQ

The correct name of I & II in the following process is :

Solid \(\overset{\mathrm{I}}{\to }\)Vapours\(\overset{\mathrm{II}}{\to }\)Solid
Memory Based Question 28/Jan/25 Evening shift

a

I \(\to\)Sublimation

II \(\to\)Vaporisation

b

I Sublimation

II Decomposition

c

I Sublimation

II Deposition

d

I Deposition

II Sublimation

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Q63
PYQ

Which of the following mixing of 1 M base and 1 M acid leads to the largest increase in temperature?

[JEE Main 2025, 24 Jan (Shift 2)]

a

\(45\mathrm{mL}{\mathrm{CH}}_{3}\mathrm{COOH}\) and 25 mL NaOH

b

\(30\mathrm{mL}{\mathrm{CH}}_{3}\mathrm{CHCOOH}\) and 30 mL NaOH

c

50 mL HCl and 20 mL NaOH

d

30 mL HCl and 30 mL NaOH

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Q64
PYQ

The number of moles of methane required to produce 11g CO2(g) after complete combustion is:

(Given molar mass of methane in g mol–1 : 16)

a

0.75

b

0.25

c

0.35

d

0.5

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Q65
PYQ

Choose the incorrect statement about Dalton's atomic theory.

a

Atoms are indivisible particles that cannot be created or destroyed in a chemical reaction.

b

Atoms of different elements have same masses and chemical properties

c

The relative number and kinds of atoms are constant in a given compound

d

Atoms of a given element have identical masses and chemical properties.

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Q66
PYQ

\(2.8\times {10}^{-3}\mathrm{mol}\mathrm{of}{\mathrm{CO}}_{2}\)is left after removing \({10}^{21}\)molecules from its ' x ' mg sample. The mass of \({\mathrm{CO}}_{2}\) taken initially is

(Given : \({\mathrm{N}}_{\mathrm{A}}=6.02\times {10}^{23}{\mathrm{mol}}^{-1}\))

[JEE Main 2025, 23 Jan (Shift 1)]

a

48.2 mg

b

98.3 mg

c

150.4 mg

d

196.2 mg

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Q67
PYQ

In a compound contains 54.2 % carbon, 9.2 % of hydrogen and rest are oxygen. What is molecular formula of compound, if molecular mass is 132 g/mol ?

a

\({\mathrm{C}}_{6}{\mathrm{H}}_{12}{\mathrm{O}}_{3}\)

b

\({\mathrm{C}}_{4}{\mathrm{H}}_{12}{\mathrm{O}}_{3}\)

c

\({\mathrm{C}}_{4}{\mathrm{H}}_{12}{\mathrm{O}}_{6}\)

d

\({\mathrm{C}}_{6}{\mathrm{H}}_{13}{\mathrm{O}}_{3}\)

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Q68
PYQ

Given below are two statements.

Statement-I: One mole of propyne reacts with excess of sodium to liberate half a mole of hydrogen gas.

Statement-II: Four grams of propyne reacts with sodium amide to liberate ammonia gas which occupies 224 mL at STP.

In the light of above statements, choose most appropriate answer from options given below

[JEE Main 2025, 22 Jan (Shift 1)]

a

Statement-I is correct but statement-II is incorrect

b

Both statement-I and statement-II are incorrect

c

Statement-I is incorrect but statement-II is correct

d

Both statement-I and statement-II are correct

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Q69
PYQ

Choose the Incorrect Statement about Dalton's Atomic Theory

a

Compounds are formed when atoms of different elements combine in any ratio

b

All the atoms of a given element have identical properties including identical mass

c

Matter consists of indivisible atoms

d

Chemical reactions involve reorganization of atoms

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Q70
PYQ

Combustion of glucose \(\left( C _6 H _{12} O _6\right)\) produces \(CO _2\) and water. The amount of oxygen (in g) required for the complete combustion of \(900 g\) of glucose is :
[Molar mass of glucose in \(g mol ^{-1}=180\) ]

[JEE Main 2024, 08 Apr (Shift 1)]

a

480

b

960

c

800

d

32

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Q71
PYQ

Combustion of glucose \(\left( C _6 H _{12} O _6\right)\) produces \(CO _2\) and water. The amount of oxygen (in g) required for the complete combustion of \(900 g\) of glucose is :
[Molar mass of glucose in \(g mol ^{-1}=180\) ]

[JEE Main 2024, 08 Apr (Shift 1)]

a

480

b

960

c

800

d

32

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Q72
PYQ

For the given reaction:

CaCO3 + 2HCl → CaCl2 + H2O + CO2

If 90g CaCO3 is added to 300 mL of HCl which contains 38.55% HCl by mass and has density 1.13 g mL–1, then which of the following option is correct?

Given molar mass of H, Cl, Ca and O are 1, 35.5, 40 and 16 g mol–1 respectively.

[JEE Main 2026, 28 Jan (Shift 2)]

a

64.97 g of HCl remains unreacted

b

60.32 g of HCl remain unreacted

c

97.30 g of HCl reacted

d

32.85 g of CaCO3 remains unreacted

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Q73
PYQ

The number of moles of methane required to produce 11g CO2(g) after complete combustion is:

(Given molar mass of methane in g mol–1 : 16)

a

0.75

b

0.25

c

0.35

d

0.5

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Q74
PYQ

For the given reaction:

CaCO3 + 2HCl → CaCl2 + H2O + CO2

If 90g CaCO3 is added to 300 mL of HCl which contains 38.55% HCl by mass and has density 1.13 g mL–1, then which of the following option is correct?

Given molar mass of H, Cl, Ca and O are 1, 35.5, 40 and 16 g mol–1 respectively.

[JEE Main 2026, 28 Jan (Shift 2)]

a

64.97 g of HCl remains unreacted

b

60.32 g of HCl remain unreacted

c

97.30 g of HCl reacted

d

32.85 g of CaCO3 remains unreacted

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Q75
PYQ

Consider the following reaction :
\[3 PbCl _2+2\left( NH _4\right)_3 PO _4 \rightarrow Pb _3\left( PO _4\right)_2+6 NH _4 Cl\]

If \(72 mmol\) of \(PbCl _2\) is mixed with \(50 mmol\) of \(\left( NH _4\right)_3 PO _4\), then the amount of \(Pb _3\left( PO _4\right)_2\) formed is ________mmol (nearest integer).

a

20

b

22

c

24

d

26

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Q76
PYQ

An organic compound gives 0.220 g of CO₂ and 0.126 g of H₂O on complete combustion. If the percentage of carbon in the compound is 24%, then the percentage of hydrogen is ___ × 10⁻¹. (Nearest integer)

[JEE Main 2023, 13 Apr (Shift 1)]

a

56

b

58

c

60

d

62

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Q77
PYQ

The ammonia \( \left(\mathrm{NH}_{3}\right) \) released on quantitative reaction of \( 0.6 \mathrm{~g} \) urea \( \left(\mathrm{NH}_{2} \mathrm{CONH}_{2}\right) \) with sodium hydroxide \( (\mathrm{NaOH}) \) can be neutralized by:

a

\(100 \text{ mL of } 0.1 \text{ N HCl}\)

b

\(200 \text{ mL of } 0.4 \text{ N HCl}\)

c

\(200 \text{ mL of } 0.2 \text{ N HCl}\)

d

\(100 \text{ mL of } 0.2 \text{ N HCl}\)

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Q78
PYQ

If 5 moles of \(\mathrm{BaCl}_{2}\) is mixed with 2 moles of \(\mathrm{Na}_{3} \mathrm{PO}_{4}\), the maximum number of moles of \(\mathrm{Ba}_{3}\left(\mathrm{PO}_{4}\right)_{2}\) formed is...............(Nearest integer)

[JEE Main 2023, 6 Apr (Shift 1)]

a

1

b

2

c

3

d

4

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Q79
PYQ

\({\text{2IO}}_{3}^{-}+x{\text{I}}^{-}+12{\text{H}}^{+}\to 6{\text{I}}_{2}+6{\text{H}}_{2}O\) What is the value of x?

[JEE Main 2023, 8 Apr (Shift 1)]

a

12

b

2

c

6

d

10

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Q80
PYQ

Which of the following have same number of significant figures?

(A) 0.00253
(B) 1.0003
(C) 15.0
(D) 163

Choose the correct answer from the options given below

[JEE Main 2023, 8 Apr (Shift 2)]

a

A, B and C only

b

C and D only

c

A, C and D only

d

B and C only

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Q81
PYQ

Zinc reacts with hydrochloric acid to give hydrogen and zinc chloride. The volume of hydrogen gas produced at STP from the reaction of \(11.5 \mathrm{~g}\) of zinc with excess \(\mathrm{HCl}\) is ............. \(\mathrm{L}\) (Nearest integer)

(Given : Molar mass of \(\mathrm{Zn}\) is \(65.4 \mathrm{~g} \mathrm{~mol}^{-1}\) and Molar volume of \(\mathrm{H}_{2}\) at \(\mathrm{STP}=22.7 \mathrm{~L}\) )

[JEE Main 2023, 31 Jan (Shift 1)]

a

1

b

2

c

3

d

4

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Q82
PYQ

The number of atoms in \(8 \mathrm{~g}\) of sodium is \(x \times 10^{23}\). The value of \(x\) is (Nearest integer)
[Given : \(\mathrm{N}_{\mathrm{A}}=6.02 \times 10^{23} \mathrm{~mol}^{-1}\)
Atomic mass of \(\mathrm{Na}=23.0 \mathrm{u}]\)

[JEE Main 2021, 1 Sep (Shift 2)]

a

1

b

2

c

3

d

4

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Q83
PYQ

A \(20\mathrm{mL}\) solution containing \(0.2\mathrm{g}\) impure \({\mathrm{H}}_{2}{\mathrm{O}}_{2}\) reacts completely with \(0.316\mathrm{g}\) of \({\mathrm{KMnO}}_{4}\) in acid solution. The purity of \({\mathrm{H}}_{2}{\mathrm{O}}_{2}\) (in %) is.......... (mol wt. of \({\mathrm{H}}_{2}{\mathrm{O}}_{2}\) = \(34\), mol wt. of \({\mathrm{KMnO}}_{4}\) = \(158\))

a

\(85\)

b

\(75\)

c

\(65\)

d

\(70\)

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Q84
PYQ

A metal chloride contains \(55.0 \%\) of chlorine by weight. \(100 \mathrm{~mL}\) vapours of the metal chloride at STP weigh \(0.57 \mathrm{~g}\). The molecular formula of the metal chloride is (Given: Atomic mass of chlorine is \(35.5 \mathrm{u}\) )

a

\(\mathrm{MCl}_{2}\)

b

\(\mathrm{MCl}_{4}\)

c

\(\mathrm{MCl}_{3}\)

d

\(\mathrm{MCl}\)

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Q85
PYQ

\(4 \mathrm{~g}\) equimolar mixture of \(\mathrm{NaOH}\) and \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) contains \(\mathrm{x} ~g\) of \(\mathrm{NaOH}\) and \(y ~g\) of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\). The value of 'x' is ____ (Nearest Integer)

a

1

b

2

c

3

d

4

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Q86
PYQ

\(0.5 \mathrm{~g}\) of an organic compound (X) with \(60 \%\) carbon will produce__________\(\times 10^{-1} \mathrm{~g}\) of \(\mathrm{CO}_{2}\) on complete combustion.

a

11

b

12

c

23

d

45

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Q87
PYQ

\(250\mathrm{mL}\) of \(0.5\mathrm{M}\mathrm{NaOH}\) was added to \(500\mathrm{mL}\) of 1 M HCl. The number of unreacted \(\mathrm{HCl}\) molecules in the solution after complete reaction is ___________\(\times {10}^{21}\) (Nearest integer) \(\left({\mathrm{N}}_{\mathrm{A}}=6.023\times {10}^{23}\right)\)

[JEE Main 2021, 20 Jul (Shift 1)]

a

225

b

226

c

227

d

228

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Q88
PYQ

When a hydrocarbon A undergoes complete combustion it requires \( 11 \) equivalents of oxygen and produces \( 4 \) equivalents of water. What is the molecular formula of A?

a

\( \mathrm{C}_{9} \mathrm{H}_{8} \)

b

\( \mathrm{C}_{11} \mathrm{H}_{4} \)

c

\( \mathrm{C}_{5} \mathrm{H}_{8} \)

d

\( \mathrm{C}_{11} \mathrm{H}_{8} \)

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Q89
PYQ

An analyst wants to convert. \(1L\mathrm{HCl}\) of \(\mathrm{pH}=1\) to a solution of \(\mathrm{HCl}\) of \(\mathrm{pH}2\). The volume of water needed to do this dilution is \(\mathrm{mL}\). (Nearest Integer)

[JEE Main 2023, 12 Apr (Shift 1)]

a

9000

b

8000

c

7000

d

6000

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Q90
PYQ

The number of molecules and moles in 2.8375 litres of \(\mathrm{O}_{2}\) at STP are respectively

[JEE Main 2023, 10 Apr (Shift 1)]

a

\(7.527 \times 10^{22}\) and \(0.250 \mathrm{~mol}\)

b

\(1.505 \times 10^{23}\) and \(0.250 \mathrm{~mol}\)

c

\(7.527 \times 10^{23}\) and \(0.125 \mathrm{~mol}\)

d

\(7.527 \times 10^{22}\) and \(0.125 \mathrm{~mol}\)

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Q91
PYQ

The volume of \(0.02\mathrm{M}\) aqueous HBr required to neutralize \(10.0\mathrm{mL}\) of \(0.01\mathrm{M}\) aqueous \(\mathrm{Ba}(\mathrm{OH}{)}_{2}\) is (Assume complete neutralization)

[JEE Main 2023, 6 Apr (Shift 2)]

a

2.5 ml

b

5.0 ml

c

10.0 ml

d

7.5 ml

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Q92
PYQ

The volume of hydrogen liberated at STP by treating \(2.4 \mathrm{~g}\) of magnesium with excess of hydrochloric acid is ...... \(\times 10^{-2} \mathrm{~L}\)

Given: Molar volume of gas is \(22.4 \mathrm{~L}\) at STP. Molar mass of magnesium is \(24 \mathrm{~g} \mathrm{~mol}^{-1}\)

[JEE Main 2023, 11 Apr (Shift 2)]

a

224

b

227

c

230

d

233

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Q93
PYQ

Aluminium reacts with sulfuric acid to form aluminium sulfate and hydrogen. What is the volume of hydrogen gas in liters (L) produced at \(300 \mathrm{~K}\) and \(1.0 \mathrm{~atm}\) pressure, when \(5.4 \mathrm{~g}\) of aluminium and \(50.0 \mathrm{~mL}\) of \(5.0 \mathrm{~M}\) sulfuric acid are combined for the reaction?

(Use molar mass of aluminium as \(27.0 \mathrm{~g} \mathrm{~mol}^{-1}, \mathrm{R}=0.082\) atm \(\mathrm{L} \mathrm{mol}^{-1} \mathrm{~K}^{-1}\) )

a

6

b

7

c

8

d

9

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Q94
PYQ

The volume (in mL) of 0.125 M AgNO₃ required to quantitatively precipitate chloride ions present in 0.3 g of [Co(NH₃)₆]Cl₃ is ______.
(Molar mass of [Co(NH₃)₆]Cl₃ = 267.46 g/mol)

[JEE Main 2020, 8 Jan (Shift 1)]

a

27

b

25

c

23

d

21

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