JEEChemistry

General Principles and Processes of Isolation of Elements

45 JEE Chemistry previous year questions on General Principles and Processes of Isolation of Elements — options free on every question; 4 include the answer & explanation free, the rest unlock with PYQ Pass.

Q1 FREE PREVIEW
PYQ

The chemical composition of ’slag’ formed during the smelting process in the extraction of copper is:

a

\(C{u}_{2}O+FeS\)

b

\(FeSi{O}_{3}\)

c

\(CuFe{S}_{2}\)

d

\(C{u}_{2}S+FeO\)

✓ Correct answer: b)

\(FeSi{O}_{3}\)

Explanation

During the extraction of copper, iron is present in the ore as impurity (FeS). The ore together with a little coke and silica is smelted; FeS present as impurity in the ore is oxidized to iron oxide, which then reacts with silica to form fusible ferrous silicate which is removed as slag. \(2FeS+3{O}_{2}\to 2FeO+2S{O}_{2}\) \(FeO+Si{O}_{2}\to \underset{\left(Slag\right)}{FeSi{O}_{3}}\)

Q2 FREE PREVIEW
PYQ

\(\mathrm{Al}_2 \mathrm{O}_3\) was leached with alkali to get \(\mathrm{X}\). The solution of X on passing of gas \(\mathrm{Y}\), forms \(\mathrm{Z}\). X, Y and \(Z\), respectively, are

a

\(\mathrm{X}=\mathrm{Na}\left[\mathrm{Al}(\mathrm{OH})_4\right], \mathrm{Y}=\mathrm{SO}_2, \mathrm{Z}=\mathrm{Al}_2 \mathrm{O}_3\)

b

\(\mathrm{X}=\mathrm{Na}\left[\mathrm{Al}(\mathrm{OH})_4\right],\mathrm{Y}=\mathrm{CO}_2, \mathrm{Z}=\) \(\mathrm{Al}_2 \mathrm{O}_3 \cdot \mathrm{xH}_2 \mathrm{O}\)

c

\(\mathrm{X}=\mathrm{Al}(\mathrm{OH})_3, \mathrm{Y}=\mathrm{CO}_2, \mathrm{Z}=\mathrm{Al}_2 \mathrm{O}_3\)

d

\(\mathrm{X}=\mathrm{Al}(\mathrm{OH})_3, \mathrm{Y}=\mathrm{SO}_2, \mathrm{Z}=\mathrm{Al}_2 \mathrm{O}_3 \cdot \mathrm{xH}_2 \mathrm{O}\)

✓ Correct answer: b)

\(\mathrm{X}=\mathrm{Na}\left[\mathrm{Al}(\mathrm{OH})_4\right],\mathrm{Y}=\mathrm{CO}_2, \mathrm{Z}=\) \(\mathrm{Al}_2 \mathrm{O}_3 \cdot \mathrm{xH}_2 \mathrm{O}\)

Explanation

When bauxite (\(Al_{2}O_{3}\)) is leached with a hot, concentrated solution of sodium hydroxide (\(NaOH\)), it dissolves to form soluble sodium tetrahydroxoaluminate(III) (or sodium aluminate)
The aluminate solution is then neutralized by passing carbon dioxide (\(CO_{2}\)) gas through it. This induces the precipitation of hydrated aluminum oxide.
\({\mathrm{Al}}_{2}{\mathrm{O}}_{3}(\mathrm{s})+2\mathrm{NaOH}(\mathrm{aq})+3{\mathrm{H}}_{2}\mathrm{O}(\mathrm{l})\to 2\mathrm{Na}[\mathrm{Al}{(\mathrm{OH})}_{4}](\mathrm{aq})\\ 2\mathrm{Na}[\mathrm{Al}{(\mathrm{OH})}_{4}](\mathrm{aq})+{\mathrm{CO}}_{2}(\mathrm{g})\to {\mathrm{Al}}_{2}{\mathrm{O}}_{3}.{\mathrm{xH}}_{2}\mathrm{O}(\mathrm{s})+2{\mathrm{NaHCO}}_{3}(\mathrm{aq})\\ \mathrm{X}=\mathrm{Na}[\mathrm{Al}{(\mathrm{OH})}_{4}](\mathrm{aq}),\mathrm{Y}={\mathrm{CO}}_{2}(\mathrm{g}),\mathrm{Z}={\mathrm{Al}}_{2}{\mathrm{O}}_{3}.{\mathrm{xH}}_{2}\mathrm{O}(\mathrm{s})\)

Q3 FREE PREVIEW
PYQ

The chemical composition of ’slag’ formed during the smelting process in the extraction of copper is:

a

\(C{u}_{2}O+FeS\)

b

\(FeSi{O}_{3}\)

c

\(CuFe{S}_{2}\)

d

\(C{u}_{2}S+FeO\)

✓ Correct answer: b)

\(FeSi{O}_{3}\)

Explanation

During the extraction of copper, iron is present in the ore as impurity (FeS). The ore together with a little coke and silica is smelted; FeS present as impurity in the ore is oxidized to iron oxide, which then reacts with silica to form fusible ferrous silicate which is removed as slag. \(2FeS+3{O}_{2}\to 2FeO+2S{O}_{2}\) \(FeO+Si{O}_{2}\to \underset{\left(Slag\right)}{FeSi{O}_{3}}\)

Q4 FREE PREVIEW
PYQ

The ore that contains both iron and copper is

a

malachite

b

azurite

c

dolomite

d

copper pyrites

✓ Correct answer: d)

copper pyrites

Explanation

Copper pyrites (also called chalcopyrite) is an ore containing both copper and iron. Its chemical formula is CuFeS₂.

  • Malachite → CuCO₃·Cu(OH)₂ (copper ore)
  • Azurite → 2CuCO₃·Cu(OH)₂ (copper ore)
  • Dolomite → CaMg(CO₃)₂ (calcium and magnesium mineral)
  • Copper pyrites (Chalcopyrite)CuFeS₂ (contains both copper and iron)

Answer: D. Copper pyrites

Q5
PYQ

The major components of German Silver are:

[JEE Main 2021, 25 Feb (Shift 2)]

a

\(Cu , Zn\) and \(Ag\)

b

\(Ge , Cu\) and \(Ag\)

c

\(Cu , Zn\) and \(Ni\)

d

\(Zn , Ni\) and \(Ag\)

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Q6
PYQ

In the extraction of copper, its sulphide ore is heated in a reverberatory furnace after mixing with silica to :

a

separate \(CuO\) as \(CuSiO _3\)

b

remove calcium as \(CaSiO _3\)

c

decrease the temperature needed for roasting of \(Cu _2 S\)

d

remove \(FeO\) as \(FeSiO _3\)

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Q7
PYQ

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): In the Ellingham diagram, a sharp change in slope of the line is observed for
\[Mg \rightarrow MgO \text { at } \sim 1120^{\circ} C\]

Reason (R): There is a large change of entropy associated with the change of state

In the light of the above statements, choose the correct answer from the options given below:

a

Both (A) and (R) are true but (R) is NOT the correct explanation of (A)

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

(A) is false but ( \(R )\) is true

d

(A) is true but \(( R )\) is false

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Q8
PYQ

Which one of the following is not an example of calcination?

[JEE Main 2023, 15 Apr (Shift 1)]

a

\(Fe _2 O _3 \cdot xH _2 O \xrightarrow{\Delta} Fe _2 O _3+ xH _2 O\)

b

\(CaCO _3 \xrightarrow{\Delta} CaO + CO _2\)

c

\(CaCO _3 \cdot MgCO _3 \xrightarrow{\Delta} CaO + MgO +2 CO _2\)

d

\(2 PbS +3 O _2 \xrightarrow{\Delta} 2 PbO +2 SO _2\)

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Q9
PYQ

Which one of the following is most likely a mismatch?

[JEE Main 2023, 13 Apr (Shift 1)]

a

Zinc - Liquation

b

Titanium - van Arkel method

c

Nickel - Mond process

d

Copper - Electrolysis

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Q10
PYQ

The chemical that is added to reduce the melting point of the reaction mixture during the extraction of aluminium is:

[JEE Main 2021, 18 Mar (Shift 1)]

a

Kaolite

b

Bauxite

c

Calamine

d

Cryolite

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Q11
PYQ

Consider two chemical reactions \( (\mathrm{A}) \) and (B) that take place during metallurgical process

(A) \( \mathrm{ZnCO}_{3} \) (s) \( \rightarrow \mathrm{ZnO}+\mathrm{CO}_{2} \)

(B) \( 2 \mathrm{~ZnS}+3 \mathrm{~O}_{2} \rightarrow 2 \mathrm{~ZnO}+2 \mathrm{~SO}_{2} \)

The correct option of names given to them respectively is

[JEE Main 2021, 20 Jul (Shift 2)]

a

(A) is calcination and (B) is roasting.

b

Both (A) and (B) are producing same product so both are roasting.

c

Both (A) and (B) are producing same product so both are calcination.

d

(A) is roasting and (B) is calcination.

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Q12
PYQ

Ellingham diagram is a graphical representation of:

a

\(\Delta G\) Vs P

b

\(\Delta H\) Vs T

c

\((\Delta G - T \Delta S ) vs T\)

d

\(\Delta G\) Vs T

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Q13
PYQ

Given below are two statements related to Ellingham diagram:
Statement-I : Ellingham diagrams can be constructed for formation of oxides, sulfides and halides of metals.
Statement-II : It consists of plots of \(\Delta_{ f} H ^0\) vs T for formation of oxides of elements.

In the light of the above statements, choose the most appropriate answer from the options given below:

[JEE Main 2023, 13 Apr (Shift 2)]

a

Both Statement-I and Statement-II are incorrect.

b

Statement-I is incorrect but Statement-II is correct.

c

Both Statement-I and Statement-II are correct.

d

Statement-I is correct but Statement-II is incorrect.

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Q14
PYQ

In the extraction of copper, its sulphide ore is heated in a reverberatory furnace after mixing with silica to:

[JEE Main 2023, 30 Jan (Shift 1)]

a

Separate \(CuO\) as \(CuSiO _3\)

b

Remove calcium as \(CuSiO _3\)

c

Decrease the temperature needed for roasting of \(Cu _2 S\)

d

Remove \(FeO\) as \(FeSiO _3\)

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Q15
PYQ

Which of the following reduction reaction CANNOT be carried out with coke?

[JEE Main 2021, 16 Mar (Shift 2)]

a

\(\mathrm{Fe}_2 \mathrm{O}_3 \rightarrow \mathrm{Fe}\)

b

\(\mathrm{ZnO} \rightarrow \mathrm{Zn}\)

c

\(\mathrm{Cu}_2 \mathrm{O} \rightarrow \mathrm{Cu}\)

d

\(\mathrm{Al}_2 \mathrm{O}_3 \rightarrow \mathrm{Al}\)

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Q16
PYQ

The metal that can be purified economically by fractional distillation method is:

[JEE Main 2021, 20 Jul (Shift 1)]

a

Fe

b

Zn

c

Cu

d

Ni

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Q17
PYQ

Which one of the following reactions does not occur during extraction of copper?

a

\(2{\text{Cu}}_{2}\text{S}+3{\text{O}}_{2}\to 2{\text{Cu}}_{2}\text{O}+2{\text{SO}}_{2}\)

b

\(2\text{FeS}+3{\text{O}}_{2}\to 2\text{FeO}+2{\text{SO}}_{2}\)

c

\(\text{CaO}+{\text{SiO}}_{2}\to {\text{CaSiO}}_{3}\)

d

\(\text{FeO}+{\text{SiO}}_{2}\to {\text{FeSiO}}_{3}\)

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Q18
PYQ

Which of the following is used as a stabilizer during the concentration of sulphide ores?

[JEE Main 2023, 10 Apr (Shift 1)]

a

Pine oils

b

Xanthates

c

Fatty acids

d

Cresols

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Q19
PYQ

Given below are two statements :
Statement-I: In the metallurgy process, sulphide ore is converted to oxide before reduction.
Statement-II: Oxide ores in general are easier to reduce.

In the light of the above statements, choose the most appropriate answer from the options given below

[JEE Main 2023, 11 Apr (Shift 2)]

a

Both Statement-I and Statement-II are correct.

b

Statement-I is correct but Statement-II is incorrect.

c

Both Statement-I and Statement-II are incorrect.

d

Statement-I is incorrect but Statement-II is correct.

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Q20
PYQ

In the leaching of alumina from bauxite, the ore expected to leach out in the process by reacting with \(NaOH\) is:

[JEE Main 2021, 25 Jul (Shift 1)]

a

\(ZnO\)

b

\(Fe _2 O _3\)

c

\(SiO _2\)

d

\(TiO _2\)

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Q21
PYQ

The statement that is INCORRECT about Ellingham diagram is:

[JEE Main 2021, 27 Jul (Shift 1)]

a

Provides idea about the reaction rate.

b

provides idea about changes in the phases during the reaction

c

provides idea about free energy change.

d

provides idea about reduction of metal oxide

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Q22
PYQ

The method used for the purification of Indium is:

[JEE Main 2021, 25 Feb (Shift 2)]

a

van Arkel method

b

liquation

c

vapour phase refining

d

zone refining

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Q23
PYQ

In the extraction process of copper, the product obtained after carrying out the reactions
(i) \(2 Cu _2 S +3 O _2 \rightarrow 2 Cu _2 O +2 SO _2\)
(ii) \(2 Cu _2 O + Cu _2 S \rightarrow 6 Cu + SO _2\) is called

[JEE Main 2023, 11 Apr (Shift 1)]

a

Blister copper

b

Copper scrap

c

Reduced copper

d

Copper matte

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Q24
PYQ

Sulphide ion is soft base and its ores are common for metals.
(A) \(Pb\)
(B) \(Al\)
(C) \(Ag\)
(D) \(Mg\)

Choose the correct answer from the options given below:

[JEE Main 2021, 22 Jul (Shift 2)]

a

(A) and (D) only

b

(A) and (C) only

c

(C) and (D) only

d

(A) and (B) only

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Q25
PYQ

Among following compounds, the number of those present in copper matte is

A. \({\mathrm{CuCO}}_{3}\)
B. \({\mathrm{Cu}}_{2}\mathrm{S}\)
C. \({\mathrm{Cu}}_{2}\mathrm{O}\)
D. \(\mathrm{FeO}\)

[JEE Main 2023, 1 Feb (Shift 2)]

a

1

b

2

c

3

d

4

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Q26
PYQ

Which of the following ore is concentrated using group 1 cyanide salt?

[JEE Main 2021, 24 Feb (Shift 1)]

a

Calamine

b

Sphalerite

c

Siderite

d

Malachite

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Q27
PYQ

The standard electrode potential \(\left({\mathrm{M}}^{3+}/{\mathrm{M}}^{2+}\right)\) for V, Cr, Mn&Co are \(-0.26\mathrm{V},-0.41\mathrm{V},+1.57\mathrm{V}\) and \(+1.97\mathrm{V}\), respectively. The metal ions which can liberate \({\mathrm{H}}_{2}\) from a dilute acid are

a

\({\mathrm{V}}^{2+}\) and \({\mathrm{Mn}}^{2+}\)

b

\({\mathrm{Cr}}^{2+}\) and \(C{o}^{2+}\)

c

\({\mathrm{V}}^{2+}\) and \({\mathrm{Cr}}^{2+}\)

d

\({\mathrm{Mn}}^{2+}\) and \({\mathrm{Co}}^{2+}\)

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Q28
PYQ

Given below are two statements:
Statement-I: Sphalerite is a sulphide ore of zinc and copper glance is a sulphide ore of copper.
Statement-II: It is possible to separate two sulphide ores by adjusting proportion of oil to water or by using 'depressants' in a froth flotation method.

Choose the most appropriate answer from the options given below:

[JEE Main 2021, 26 Aug (Shift 2)]

a

Both Statement-I and Statement-II are false.

b

Both Statement-I and Statement-II are true.

c

Statement-I is true but Statement-II is false.

d

Statement-I is false but Statement-II is true.

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Q29
PYQ

Assertion (A): Aluminium is extracted from bauxite by the electrolysis of molten mixture of \(Al _2 O _3\) with cryolite.
Reason (R): The oxidation state of \(Al\) in cryolite is +3 .

[JEE Main 2021, 31 Aug (Shift 1)]

a

Both assertion and reason are correct but reason is not the correct explanation of assertion

b

Both assertion and reason are correct and reason is the correct explanation of assertion

c

Assertion is true but reason is false

d

Assertion is false but reason is true.

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Q30
PYQ

Among statements (a) - (d), the correct ones are

(a) Lime stone is decomposed to \( \mathrm{CaO} \) during the extraction of iron from its oxides.

(b) In the extraction of silver, silver is extracted as an anionic complex.

(c) Nickel is purified by Monds process.

(d) \( \mathrm{Zr} \) and \( \mathrm{Ti} \) are purified by Van Arkel method.


a

(a), (c) and (d) only

b

(c) and (d) only

c

(b), (c) and (d) only

d

(a), (b), (c) and (d)

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Q31
PYQ

Which one of the following statements is incorrect?

[JEE Main 2023, 31 Jan (Shift 2)]

a

Boron and Indium can be purified by zone refining method.

b

Van- Arkel method is used to purify tungsten.

c

Cast iron is obtained by melting pig iron with scrap iron and coke using hot air blast.

d

The malleable iron is prepared from cast iron by oxidising impurities in a reverberatory furnace

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Q32
PYQ

Given below are two statements:
Statement-I: In froth floatation method a rotating paddle agitates the mixture to drive air out of it.
Statement-II: Iron pyrites are generally avoided for extraction of iron due to environmental reasons.

In the light of the above statements, choose the correct answer from the options given below:

[JEE Main 2023, 25 Jan (Shift 2)]

a

Both Statement-I and Statement-II are true

b

Statement-I is false but Statement-II is true

c

Statement-I is true but Statement-II is false

d

Both Statement-I and Statement-II are false

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Q33
PYQ

The major components in Gun Metal are:

[JEE Main 2021, 24 Feb (Shift 1)]

a

\( \mathrm{Cu}, \mathrm{Zn} \) and \( \mathrm{Ni} \)

b

\( \mathrm{Cu}, \mathrm{Sn} \) and \( \mathrm{Zn} \)

c

\( \mathrm{Al}, \mathrm{Cu}, \mathrm{Mg} \) and \( \mathrm{Mn} \)

d

\( \mathrm{Cu}, \mathrm{Ni} \) and \( \mathrm{Fe} \)

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Q34
PYQ

Statement I: During Electrolytic refining, the pure metal is made to act as anode and its impure metallic form is used as cathode.
Statement II: During the Hall-Heroult electrolysis process, purified \(Al _2 O _3\) is mixed with \(Na _3 AlF _6\) to lower the melting point of the mixture. In the light of the above statements, choose the most appropriate answer from the options given below:

a

Statement I is incorrect but Statement II is correct

b

Both Statement I and Statement II are incorrect

c

Statement I is correct but Statement II is incorrect

d

Both Statement I and Statement II are correct

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Q35
PYQ

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): In an Ellingham diagram, the oxidation of carbon to carbon monoxide shows a negative slope with respect to temperature.
Reason (R): CO tends to get decomposed at higher temperature.

In the light of the above statements, choose the correct answer from the options given below

[JEE Main 2023, 1 Feb (Shift 1)]

a

Both (A) and (R) are correct and (R) is the correct explanation of (A)

b

(A) is not correct but (R) is correct

c

Both (A) and (R) are correct but (R) is NOT the correct explanation of (A)

d

(A) is correct but (R) is not correct

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Q36
PYQ

The addition of silica during the extraction of copper from its sulphide ore

[JEE Main 2021, 27 Jul (Shift 2)]

a

reduces copper sulphide into metallic copper

b

reduces the melting point of the reaction mixture

c

converts copper sulphide into copper silicate

d

converts iron oxide into iron silicate

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Q37
PYQ

The methods NOT involved in concentration of ore are
(A) Liquation
(B) Leaching
(C) Electrolysis
(D) Hydraulic washing
(E) Froth floatation

Choose the correct answer from the options given below:

[JEE Main 2023, 31 Jan (Shift 1)]

a

B, D and C only

b

C, D and E only

c

A and C only

d

B, D and E only

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Q38
PYQ

The major components of German Silver are:

a

\(Cu , Zn\) and \(Ag\)

b

\(Ge , Cu\) and \(Ag\)

c

\(Cu , Zn\) and \(Ni\)

d

\(Zn , Ni\) and \(Ag\)

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Q39
PYQ

The process that involves the removal of sulphur from the ores is:

[JEE Main 2021, 16 Mar (Shift 1)]

a

Smelting

b

Leaching

c

Refining

d

Roasting

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Q40
PYQ

In the electrolytic refining of blister copper, the total number of main impurities, from the following, removed as anode mud is________.
\(Pb , Sb , Se , Te , Ru , Ag , Au\) and \(Pt\)

[JEE Main 2021, 31 Aug (Shift 2)]

a

6

b

5

c

4

d

3

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Q41
PYQ

Which one of the following reactions does not occur during extraction of copper?

[JEE Main 2023, 25 Jan (Shift 1)]

a

\(2 Cu _2 S +3 O _2 \rightarrow 2 Cu _2 O +2 SO _2\)

b

\(2 FeS +3 O _2 \rightarrow 2 FeO +2 SO _2\)

c

\(CaO + SiO _2 \rightarrow CaSiO _3\)

d

\(FeO + SiO _2 \rightarrow FeSiO _3\)

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Q42
PYQ

The metal which is extracted by oxidation and subsequent reduction from its ore is:

[JEE Main 2023, 24 Jan (Shift 2)]

a

\(Al\)

b

\(Ag\)

c

\(Cu\)

d

\(Fe\)

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Q43
PYQ

Match list-I with list-II:

List-I

List-II

(I)

Mercury

(P)

Vapour phase refining

(II)

Copper

(Q)

Distillation refining

(II)

Silicon

(R)

Electrolytic refining

(IV)

Nickel

(S)

Zone refining

Choose the most appropriate answer from the option given below:

[JEE Main 2021, 18 Mar (Shift 2)]

a

I\(\to\)P, II\(\to\)S, III\(\to\)Q, IV\(\to\)R

b

I\(\to\)Q, II\(\to\)R, III\(\to\)P, IV\(\to\)S

c

I\(\to\)Q, II\(\to\)R, III\(\to\)S, IV\(\to\)P

d

I\(\to\)Q, II\(\to\)S, III\(\to\)R, IV\(\to\)P

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Q44
PYQ

The major component of which of the following ore is sulphide based mineral?

[JEE Main 2023, 29 Jan (Shift 2)]

a

Calamine

b

Siderite

c

Sphalerite

d

Malachite

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Q45
PYQ

Calamine and Malachite, respectively, are the ores of:

[JEE Main 2021, 1 Sep (Shift 2)]

a

Copper and Iron

b

Aluminium and Zinc

c

Nickel and Aluminium

d

Zinc and copper

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