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The species formed on fluorination of phosphorus pentachloride in a polar organic solvent are [JEE Advanced 2024, Paper-…

Q1

The species formed on fluorination of phosphorus pentachloride in a polar organic solvent are

[JEE Advanced 2024, Paper-2]

a

\({\left[{\mathrm{PF}}_{4}\right]}^{+}{\left[{\mathrm{PF}}_{6}\right]}^{-}\)and \({\left[{\mathrm{PCl}}_{4}\right]}^{+}{\left[{\mathrm{PF}}_{6}\right]}^{-}\)

b

\({\left[{\mathrm{PCl}}_{4}\right]}^{+}{\left[{\mathrm{PCl}}_{4}{\mathrm{F}}_{2}\right]}^{-}\)and \({\left[{\mathrm{PCl}}_{4}\right]}^{+}{\left[{\mathrm{PF}}_{6}\right]}^{-}\)

c

\({\mathrm{PF}}_{3}\) and \({\mathrm{PCl}}_{3}\)

d

\({\mathrm{PF}}_{5}\) and \({\mathrm{PCl}}_{3}\)

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