Arrange the following solutions in order of their increasing boiling points \(\left(\mathrm{i}\right){10}^{-4}\mathrm{M}…
Arrange the following solutions in order of their increasing boiling points
\(\left(\mathrm{i}\right){10}^{-4}\mathrm{M}\mathrm{NaCl}\\ \left(\mathrm{ii}\right){10}^{-4}\mathrm{M}\mathrm{Urea}\\ \left(\mathrm{iii}\right){10}^{-3}\mathrm{M}\mathrm{NaCl}\\ \left(\mathrm{iv}\right){10}^{-2}\mathrm{M}\mathrm{NaCl}\)
(ii) < (i) < (iii) < (iv)
\(∆{\mathrm{T}}_{\mathrm{b}}={\mathrm{iK}}_{\mathrm{b}}\mathrm{m}\)
\(∆{\mathrm{T}}_{\mathrm{b}}\alpha \mathrm{i}\times \mathrm{m}\)
For NaCl " i " = 2 and Urea " i " = 1
Higher the product of vant Hoff factor and concentration higher the boiling point.
i × C = (i) 2 × 10–4 (ii) 1 × 10–4 (iii) 2 × 10–3 (iv) 2 × 10–2
Hence the order for boiling point is: (ii) < (i) < (iii) < (iv)
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