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An organic compound has 42.1% carbon, 6.4% hydrogen and remainder is oxygen. If its molecular weight is 342, then its mo…

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An organic compound has 42.1% carbon, 6.4% hydrogen and remainder is oxygen. If its molecular weight is 342, then its molecular formula is:

a

C11H18O12

b

C12H20O12

c

C14H20O10

d

C12H22O11

✓ Correct answer: d)

C12H22O11

Explanation

Given:

C = 42.1%, H = 6.4%, O = 100 − 48.5 = 51.5%

Divide by atomic masses:

C → 42.1 ÷ 12 = 3.508

H → 6.4 ÷ 1 = 6.4

O → 51.5 ÷ 16 = 3.219

Divide all by 3.219:

C ≈ 1.09, H ≈ 1.99, O ≈ 1

Empirical formula ≈ C₁H₂O₁

Empirical mass = 12 + 2 + 16 = 30

n = 342 ÷ 30 = 11.4 ≈ 11

Molecular formula = C₁₁H₂₂O₁₁

Answer: Option D

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